ar X iv : 0 90 9 . 33 58 v 1 [ co nd - m at . s up r - co n ] 1 8 Se p 20 09 Possible Microscopic Doping Mechanism in Tl - 2201

نویسندگان

  • D. C. Peets
  • D. G. Hawthorn
  • Ruixing Liang
  • D. A. Bonn
  • W. N. Hardy
چکیده

X-ray absorption spectroscopy on oxygen-annealed, self-flux-grown single crystals of Tl2Ba2CuO6+δ suggests a microscopic doping mechanism whereby interstitial oxygens are attracted to copper substituted on the thallium site, contributing holes to both the planes and to these coppers, and typically promoting only one hole to the plane rather than two. These copper substituents would provide an intrinsic hole doping. The evidence for this is discussed, along with an alternative interpretation.

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تاریخ انتشار 2009